Synthesis and Investigation of Zinc(Ii) Nitrate Complexes With Thiadiazole–1,3,4 Derivatives
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This article presents methods for the synthesis of new complex compounds of zinc(II) with 2-aminothiadiazole-1,3,4 (AT) structure [Zn(AT)3(NO3)2] and 2-amino-5-methylthiadiazole-1,3,4 (AMT) structure [Zn(AMT)3(NO3)2]. The structure of the obtained complexes was established by the methods of elemental and X-ray diffraction analyses. In complexes around the Zn(II) ion, three nitrogen atoms of thiadiazole cycles and two oxygen atoms of two nitrate anions are coordinated in the equatorial plane in axial positions.
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